The objective of this work is to test whether vibration frequencies ν1 of free, ground-state, main-group triatomic molecules manifest a periodicity similar to those of atomic spectroscopic constants. This test and an earlier test on energies of atomization underscore the role of the periodic law as a foundation of chemistry. Using data from four data bases and from computation, we have collected and have mapped ν1 data in mathematical spaces of fixed-period molecules. These spaces are 8×8×8 atom cubes with rare-gas molecules on each face. The ν1 collected from various sources might be of use in optical or near-optical searches for cold triatomics in interstellar space.
Comments: 20 Pages.
Unique-IP document downloads: 55 times
Add your own feedback and questions here:
You are equally welcome to be positive or negative about any paper but please be polite. If you are being critical you must mention at least one specific error, otherwise your comment will be deleted as unhelpful.