## Entropy：A Concept that is not a Physical Quantity

**Authors:** Shufeng-Zhang

This study has demonstrated that entropy is not a physical quantity, that is, the physical quantity called entropy does not exist. If the efficiency of heat engine is defined as η = W/W1, and the reversible cycle is considered to be the Stirling cycle, then, given ∮dQ/T = 0, we can prove ∮dW/T = 0 and ∮d/T = 0. If ∮dQ/T = 0, ∮dW/T = 0 and ∮dE/T = 0 are thought to define new system state variables, such definitions would be absurd. The fundamental error of entropy is that in any reversible process, the polytropic process function Q is not a single-valued function of T, and the key step of Σ[(ΔQ)/T)] to ∫dQ/T doesn’t hold.P-V fig. should be P-V-T fig. Similarly, ∮dQ/T = 0, ∮dW/T = 0 and ∮dE/T = 0 do not hold, either. Since the absolute entropy of Boltzmann is used to explain Clausius entropy and the unit (J/K) of the former is transformed from the latter, the non-existence of Clausius entropy simultaneously denies Boltzmann entropy.

**Comments:** 11 Pages.

**Download:** **PDF**

### Submission history

[v1] 21 Nov 2008

[v2] 2012-11-23 14:38:52

**Unique-IP document downloads:** 262 times

**Add your own feedback and questions here:**

*You are equally welcome to be positive or negative about any paper but please be polite. If you are being critical you must mention at least one specific error, otherwise your comment will be deleted as unhelpful.*

*
*