Authors: Bezverkhniy Volodymyr Dmytrovych
The present work shows the inapplicability of the Pauli principle to chemical bond, and a new theoretical model of the chemical bond is proposed based on the Heisenberg uncertainty principle. See pp. 88 - 104. Using the concept of three-electron bond we can represent the actual electron structure of benzene and other molecules, explain specificity of the aromatic bond and calculate the delocalization energy. Gives theoretical justification and experimental confirmation of existence of the three-electron bond. It was shown, that functional relation y = a + b/x + c/x^2 fully describes dependence of energy and multiplicity of chemical bond from bond distance.
Comments: 127 Pages. Biggest part of this work is published in journal "Organic Chemistry: Current Research" (2017.07.02., Volume 6, Issue 2) https://www.omicsonline.org/open-access/theory-of-threeelectron-bond-in-the-four-works-with-brief-comments-2161-0401-1000182.pdf
[v1] 2017-10-30 13:33:28
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