Climate Research

   

Reinterpreting and Augmenting John Tyndall’s 1859 Greenhouse Gas Experiment with Thermoelectric Theory and Raman Spectroscopy

Authors: Blair D. Macdonald

Climate science's fundamental premise – assumed by all parties in the great climate debate – says the greenhouse gases – constituting some 1% of Earth’s atmosphere – first derived by John Tyndall‘s in his 1859 thermopile experiment, and demonstrated graphically today by infrared IR spectroscopy – are special because of their infrared (IR) ‘heat’ absorbing property. From this, it is paradoxically assumed the (remaining 99%) non-greenhouse gases Nitrogen (N2) and Oxygen (O2) are non-heat absorbent. This paper reveals, by elementary physics, the (deceptive) role thermopiles play in this paradox. It was found: for a special group substances – all sharing (at least one) electric dipole moment – i.e. CO2, and the other greenhouse gases – thermopiles – via the thermoelectric (Seebeck) effect – generate electricity from the radiated IR. Devices using the thermopile as a detector (e.g. IR spectrographs) discriminate, and have misinterpreted IR absorption for anomalies of electricity production – between the sample gases and a control heat source. N2 and O2 were found to have (as all substances) predicted vibrational modes (derived by the Schrodinger quantum equation) at 1556cm-1 and 2330cm-1 respectively – well within the IR range of the EM spectrum and are clearly observed – as expected – with Raman Spectroscopy – IR spectroscopy’s complement instrument. The non-greenhouse gases N2 and O2 are relegated to greenhouse gases, and Earth’s atmospheric thermoelectric spectrum was produced (formally IR spectrum), and was augmented with the Raman observations. It was concluded the said greenhouses gases are not special, but typical; and all substances have thermal absorption properties, as measured by their respective heat capacities.

Comments: 32 Pages.

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Submission history

[v1] 2015-04-21 04:39:04
[v2] 2015-04-22 08:25:00
[v3] 2015-12-15 08:14:03

Unique-IP document downloads: 339 times

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